一、个人简介
1982年生于广东湛江,江南大学副教授,硕士生导师。2006年毕业于江南大学,获学士学位;2006-2008年在江南大学进行硕士阶段学习,获硕士学位;2012年毕业于复旦大学化学系,获理学博士学位,同年在复旦大学材料科学系从事博士后研究工作;2015年1月至今,在江南大学化学与材料工程学院工作。
二、研究领域
1、过渡金属参与的新反应
2、含氟精细有机化学品的合成
3、新型稀土化合物促进的C1化学
三、学术成果
(一)代表性科研项目(限5项)
1、主持国家自然科学基金面上基金项目(No.21971089)
2、含脒基或胍基的银离子和银/锌杂双金属配合物的合成及其在功能性涂料中的应用,横向项目,主持
3、主持国家自然科学基金青年基金项目(No. 21502070)
4、主持博士后科学基金面上项目(2013M531110)
5、参与国家自然科学基金地区项目(No.21562041)
(二)代表性论文(限10篇)
1、C. G. Zheng*, J. Chao, S. Huang, K. Zhao, Y. Y. Fu, M. Y. Ma,J. Q. Hong*, Transition-Metal-Free Synthesis of Aryl Trifluoromethyl Thioethers through Indirect Trifluoromethylthiolation of Sodium Arylsulfinate with TMSCF3, Org. Lett. 2021, 23, 6982-6986.
2、C. G. Zheng*, S. Huang, Y. Liu, C. Jiang, W. Zhang, G. Fang,J. Q. Hong*, Geometrically Selective Denitrative Trifluoromethylthiolation ofβ‑Nitrostyrenes with AgSCF3for (E)‑Vinyl Trifluoromethyl Thioethers, Org. Lett. 2020, 22, 4868-4872.
3、C. G. Zheng, Y. Liu,J. Q. Hong, S. Huang, W. Zhang, Y. P. Yang, G. Fang, Ag(I)-Mediated Oxidative Radical Trifluoromethylthiolation of Alkenes, Synlett2019, 30, 1324-1328.
4、J. Q. Hong, H. W. Tian, L. X. Zhang, X. G. Zhou, I. del Rosal, L. H. Weng, L. Maron, Reversing conventional reactivity of mixed oxo/alkyl rare-earth complexes: non-redox oxygen atom transfer, Angew. Chem. Int. Ed. 2018, 57, 1062 -1067.
5、J. Q. Hong, X. X. Zhang, R. X. Long, C. G. Zheng, Syntheses, crystal structures, and properties of metal (II) coordination polymers based on flexible ligand 1,3-bis(4-phenoxy)benzenedicarboxylic acid and bis(benzimidazole), Z. Anorg. Allg. Chem. 2018, 644, 518-524.
6、H. W Tian,J. Q. Hong, K. Wang, I. del Rosal, L. Maron, X. G. Zhou, L. X. Zhang, Unprecedented reaction mode of phosphorus in phosphinidene rare-earth complexes: a joint experimental−theoretical study, J. Am. Chem. Soc. 2018, 140, 102-105.
7、J. Q. Hong,G. F. Wang,L. G. Huo,C. G. Zheng, Copper-promoted conversion of aromatic amines into trifluoromethylated arenes: one-pot Sandmeyer trifluoromethylation, Chin. J. Chem.2017, 35, 1761-1767.
8、J. Q. Hong, L. G. Huo, Y. P. Yang, G. F. Wang, C. G. Zheng, Copper-promoted one-pot trifluoromethylation of aromatic amines with Togni’s reagent, ChemistrySelect 2017, 2, 3716-3720.
9、J. Q. Hong, L. G. Huo, Y. Z. Wang, R. X. Long, Changge Zheng, Syntheses, crystal structures and properties of two coordination polymers derived from flexible dicarboxylate and N-donor ligands, Inorg. Chim. Acta 2017, 455, 81–87.
10、J. Q. Hong, W. J. Zhai, L. K. Wang, Y. Z. Wang, C. G. Zheng, Syntheses, structures, and luminescence of metal (II) coordination polymers based on flexible 1,1-(1,4-butanediyl)bis(imidazole) and tetrachlorobenzene-1,4-dicarboxylate ligands,Z.Anorg. Allg. Chem. 2016, 642,1486–1492.
11、J. Q. Hong, Z. H. Li, Z. N. Chen, L. H. Weng, X. G. Zhou, L. X. Zhang, Small molecule activation by mixed methyl/methylidene rare earth metal complexes, Dalton Trans. 2016, 45, 6641–6649.
12、J. Q. Hong, L. X. Zhang, K. Wang, Z. X. Chen, L. M. Wu, X. G. Zhou, Synthesis, structural characterization, and reactivity of mono(amidinate) rare-earth-metal bis(aminobenzyl) complexes, Organometallics 2013, 32, 7312-7322.
13、J. Q. Hong, L. X. Zhang, K. Wang, Y. Zhang, L. H. Weng, X. G. Zhou, Methylidene rare-earth-metal complex mediated transformations of C=N, N=N and N–H bonds: new routes to imido rare-earth-metal clusters, Chem. Eur. J. 2013, 19, 7865-7873.
14、J. Q. Hong, L. X. Zhang, X. Y. Yu, M. Li. Z. X. Zhang, P. Z. Zheng, M. Nishiura, Z. M. Hou, X. G. Zhou, Syntheses, sructures, and reactivities of homometallic rare earth metal multimethyl methylidene and oxo complexes, Chem. Eur. J. 2011, 17, 2130-2137.
(三)代表性专利(限授权专利)
1、一种炔基脒类化合物的合成方法,ZL 201611189406.4,2019-03-15
五、联系方式
通讯地址:无锡市蠡湖大道1800号江南大学化学与材料工程学院
邮编:214122
联系电话:17715305112
Email:hongjq@jiangnan.edu.cn